MOLECULAR ARRANGEMENT OF A POLY(ACRYLONITRILE-CO-4-VINYLPYRIDINE) MONOLAYER ON WATER

被引：8

作者：

FRYSINGER, GS ^{[1
]}

BARNOSKI, AA ^{[1
]}

GAINES, GL ^{[1
]}

KORENOWSKI, GM ^{[1
]}

机构：

[1] RENSSELAER POLYTECH INST,DEPT CHEM,TROY,NY 12180

来源：

LANGMUIR | 1994年 / 10卷 / 07期

关键词：

D O I：

10.1021/la00019a042

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The copolymer film poly(acrylonitrile-co-4-vinylpyridine) has been studied at the air-water interface by second harmonic generation. These studies indicate pyridine immersion in the surface and coiling of the polymer chain containing nitrile moieties toward the vapor phase. Phase measurements on the polymer and long-chain nitrile second harmonic signals support this proposed molecular arrangement.

引用

页码：2277 / 2280

页数：4

共 7 条

[1] USE OF FILTER-PAPER WILHELMY PLATES WITH INSOLUBLE MONOLAYERS [J].