A NEW EPOXIDATION CATALYST - THE REACTIVITY AND X-RAY CRYSTAL-STRUCTURE OF [RUO2(BIPY)(IO3(OH)(3))].1.5H2O (BIPY=2,2'-BIPYRIDINE)

被引：30

作者：

BAILEY, AJ ^{[1
]}

GRIFFITH, WP ^{[1
]}

WHITE, AJP ^{[1
]}

WILLIAMS, DJ ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,INORGAN & CHEM CRYSTALLOG RES LABS,LONDON SW7 2AY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 16期

关键词：

D O I：

10.1039/c39940001833

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of [RuO2(bipy){IO3(OH)(3)}].1.5H(2)O 1 is reported: with NaIO4 or NBu(4)(n)IO(4) as cooxidant it is an efficient catalyst for alkene epoxidations under mild conditions; it also oxidises primary alcohols to aldehydes and secondary alcohols to ketones.

引用

页码：1833 / 1834

页数：2

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