REDUCTIVE CONVERSION OF CHLORODIFLUOROMETHYLBENZENE WITH SAMARIUM(II) DIIODIDE

被引：15
作者：
YOSHIDA, M
SUZUKI, D
IYODA, M
机构：
来源：
CHEMISTRY LETTERS | 1994年 / 12期
关键词：
D O I：
10.1246/cl.1994.2357
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
PhCF(2)Cl suffered readily one-electron reduction with SmI2 to give PhCF(2) radical and chloride ion. The resulting PhCF(2) radical was further reduced with SmI2 to PhCF(2)SmI(2) which reacted with electrophile such as Me(3)SiCl. The initially formed PhCF(2) radical could be trapped by olefin or acetylene before it was reduced to PhCF(2)SmI(2).
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页码：2357 / 2360
页数：4
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