ARSENIC SPECIATION BY COUPLING HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY WITH INDUCTIVELY-COUPLED PLASMA-MASS SPECTROMETRY

被引：86

作者：

DEMESMAY, C ^{[1
]}

OLLE, M ^{[1
]}

PORTHAULT, M ^{[1
]}

机构：

[1] UNIV CLAUDE BERNARD,SCI ANALYT LAB,UA 0435,F-69622 VILLEURBANNE,FRANCE

来源：

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1994年 / 348卷 / 03期

关键词：

D O I：

10.1007/BF00325361

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

An ICP-MS detector in combination with HPLC has been evaluated for the analysis of six arsenic compounds. The influence of the presence of an organic modifier in the mobile phase on arsenic response and the quality parameters of the analysis are discussed. Detection limits for arsenic species under study range from 10 to 30 pg. The determination of arsenic compounds in solutions simulating fish or sediment extracts has been used to demonstrate the applicability of this technique.

引用

页码：205 / 210

页数：6

共 18 条

[1]

ALBERT M, 1992, ANALUSIS, V20, P383

[2] SIGNAL ENHANCEMENT OF ELEMENTS DUE TO THE PRESENCE OF CARBON-CONTAINING COMPOUNDS IN INDUCTIVELY COUPLED PLASMA MASS-SPECTROMETRY [J].

ALLAIN, P ;

JAUNAULT, L ;

MAURAS, Y ;

MERMET, JM ;

DELAPORTE, T .

ANALYTICAL CHEMISTRY, 1991, 63 (14) :1497-1498

[3]

Batley G.E., 1989, TRACE ELEMENT SPECIA

[4] DETERMINATION OF ARSENIC IN SAMPLES WITH HIGH CHLORIDE CONTENT BY INDUCTIVELY COUPLED PLASMA MASS-SPECTROMETRY [J].

BRANCH, S ;

EBDON, L ;

FORD, M ;

FOULKES, M ;

ONEILL, P .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1991, 6 (02) :151-154

[5] SIMPLE APPROACH TO REDUCING POLYATOMIC ION INTERFERENCES ON ARSENIC AND SELENIUM IN INDUCTIVELY COUPLED PLASMA MASS-SPECTROMETRY [J].

EVANS, EH ;

EBDON, L .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1989, 4 (03) :299-300

[6] EFFECT OF ORGANIC-SOLVENTS AND MOLECULAR GASES ON POLYATOMIC ION INTERFERENCES IN INDUCTIVELY COUPLED PLASMA MASS-SPECTROMETRY [J].

EVANS, EH ;

EBDON, L .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1990, 5 (06) :425-429

[7]

Harrison R. M., 1989, ENV ANAL USING CHROM

[8] TRACE-ELEMENT ANALYSIS OF ORGANIC SOLUTIONS USING INDUCTIVELY COUPLED PLASMA-MASS SPECTROMETRY [J].

HAUSLER, D .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1987, 42 (1-2) :63-73

[9] APPLICATION OF INDUCTIVELY COUPLED PLASMA SOURCE-MASS SPECTROMETRY (ICP-MS) TO THE DETERMINATION OF TRACE-METALS IN ORGANICS [J].

HUTTON, RC .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1986, 1 (04) :259-263

[10] THE ACUTE TOXICITY OF ARSENOBETAINE [J].

KAISE, T ;

WATANABE, S ;

ITOH, K .

CHEMOSPHERE, 1985, 14 (09) :1327-1332

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