C-B-NMR SPECTROSCOPIC INVESTIGATION OF ALPHA-1,4-D-GLUCOSE AND BETA-1,4-D-GLUCOSE HOMOOLIGOMERS

被引：88

作者：

HEYRAUD, A

RINAUDO, M

VIGNON, M

VINCENDON, M

机构：

[1] CNRS,CTR RECH MACROMOLEC VEGETALES,F-38041 GRENOBLE,FRANCE

[2] CEN,DEPT RECH FONDAMENTALE,CHIM ORGAN PHYS LAB,F-38041 GRENOBLE,FRANCE

来源：

BIOPOLYMERS | 1979年 / 18卷 / 01期

关键词：

D O I：

10.1002/bip.1979.360180113

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A complete, unambiguous assignment of all the 13C signals of cellobiose and maltose has been achieved using methods such as selective proton decoupling, 13C selective spin labeling, and isotopic chemical shift induced by deuterium. The chemical‐shift variation of the 13C signals with the degree of polymerization in each α or β (1 → 4) series is discussed. The chemical‐shift dependence on temperature and solvent in these two series is shown and interpreted in terms of modifications of the solvation and of the conformation. Copyright © 1979 John Wiley & Sons, Inc.

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页码：167 / 185

页数：19

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