AN ASYMMETRIC-SYNTHESIS OF (R)-(+)-2-NONYL-2-(CARBOMETHOXY)-CYCLOPENTANONE, A KNOWN PRECURSOR OF THE ANTIBIOTIC (-)-MALYNGOLIDE

被引：31

作者：

GUINGANT, A

机构：

[1] Unite de Chimie Organique associée au CNRS, ESPCI, 75231 Paris Cedex 05

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 06期

关键词：

CHIRAL BETA-ENAMINO ESTER; ASYMMETRIC SYNTHESIS; LEWIS ACID; (-)MALYNGOLIDE;

D O I：

10.1016/S0957-4166(00)82165-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A synthesis of (R)-(+)-2-nonyl-2-(carbomethoxy)cyclopentanone 2 via an asymmetric Michael process involving the chiral beta-enamino ester (+)-3 is described.

引用

页码：415 / 418

页数：4

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