ANIONIC SYNTHESIS OF CHAIN-END FUNCTIONALIZED POLYMERS

被引：28
|
作者：
QUIRK, RP
YIN, J
GUO, SH
HU, XW
SUMMERS, G
KIM, JG
ZHU, LF
SCHOCK, LE
机构：
[1] Institute of Polymer Science, University of Akron, Akron, Ohio
来源：
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1990年 / 32卷
关键词：
D O I：
10.1002/masy.19900320106
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The use of living, alkyllithium‐initated anionic polymerization to prepare chain‐end functionalization reactions is discussed. The scope and limitations of termination reactions with a variety of electrophilic species is illustrated for carbonation, hydroxyethylation, amination, and sulfonation. The methodology of using substituted 1,1‐diphenylethylenes to provide a general, quantitative functionalization method is outlined and illustrated with examples of phenol end‐functionalization and amination. Copyright © 1990 Hüthig & Wepf Verlag
引用
收藏
页码：47 / 59
页数：13
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