COMPLETE DESULFURIZATION OF DIETHYLDITHIOCARBAMATO LIGANDS TO GIVE A PENTARUTHENIUM CLUSTER CONTAINING DIETHYLAMINOMETHYLIDYNE LIGANDS

被引：23

作者：

DEEMING, AJ

VAISH, R

机构：

[1] Department of Chemistry, University College London, London, WC1H 0AJ

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 460卷 / 01期

关键词：

D O I：

10.1016/0022-328X(93)80372-I

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oxidative addition of the disulfide Et2NC(S)SSC(S)NEt2 to the cluster [Ru3(CO)12] leads to the diethyldithiocarbamato complex, [Ru(Et2NCS2)2(CO)2]3, which reacts with more [Ru3(CO)12] to give mainly the pentanuclear cluster, [Ru5(mu4-S)2(mu-CNEt2)2(CO)11] 4, containing bridging diethylaminomethylidyne ligands derived by cleavage of both C-S bonds of both dithiocarbamato ligands.

引用

页码：C8 / C10

页数：3

共 9 条

[1] BOND AM, 1984, COORDIN CHEM REV, V54, P23, DOI 10.1016/0010-8545(84)85017-1
[2] Coffey Thomas, 1966, COMMUNICATION
[3] MONONUCLEAR PYRIDINE-2-THIONATO COMPLEXES FORMED DIRECTLY FROM RUTHENIUM TRICHLORIDE
DEEMING, AJ
KARIM, M
[J]. POLYHEDRON, 1991, 10 (08) : 837 - 840
[4] SUPPRESSION OF CLUSTER UNSATURATION BY FORMATION OF EXTENSIVE BUT LONG-RANGE METAL METAL-BONDING - CRYSTAL-STRUCTURES OF [RU3H(PYS)(CO)9] AND [(RU3H(PYS)(CO)7)3], WHERE PYS IS THE PYRIDINE-2-THIOLATO LIGAND
DEEMING, AJ
HARDCASTLE, KI
KARIM, M
[J]. INORGANIC CHEMISTRY, 1992, 31 (23) : 4792 - 4796
[5] SYNTHESIS, STRUCTURE, AND CHARACTERIZATION OF BIS(DIETHYLDITHIOCARBAMATO)(DIETHYLTHIOCARBAMYL)SULFIDONIOBIUM(V) AND ITS TANTALUM ANALOG
GILLETTI, PF
FEMEC, DA
KEEN, FI
BROWN, TM
[J]. INORGANIC CHEMISTRY, 1992, 31 (19) : 4008 - 4012
[6] PENTA-NUCLEAR AND HEXA-NUCLEAR RUTHENIUM MU-2-PYRIDYL COMPLEXES
HARDCASTLE, KI
COCKERTON, BR
DEEMING, AJ
KARIM, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (10): : 1607 - 1613
[7] SYNTHESIS AND STRUCTURE OF A MOLYBDENUM DIMER ILLUSTRATING D-PI ORBITAL PARTICIPATION IN PI-DONATION, PI-ACCEPTANCE, AND METAL-METAL BOND FORMATION
HERRICK, RS
NIETERBURGMAYER, SJ
TEMPLETON, JL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (09) : 2599 - 2605
[8] RICARD L, 1973, INORG CHEM, V12, P2182, DOI 10.1021/ic50127a050
[9] CARBON-SULFUR BOND CLEAVAGE - STRUCTURE OF [MO(SCNPR2)(S2CNPR2)]2S2
RICARD, L
WEISS, R
ESTIENNE, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (15) : 906 - &

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