ANOMALIES IN DIFFUSE REFLECTANCE INFRARED-SPECTRA OF WOOD AND WOOD POLYMERS

被引:20
作者
ANDERSON, TH
WEAVER, FW
OWEN, NL
机构
[1] Chemistry Department, Brigham Young University, Provo
关键词
D O I
10.1016/0022-2860(91)85072-B
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Infrared diffuse reflectance spectra of wood and some component wood polymers as well as benzoic acid are compared with the corresponding spectra taken in transmittance using KBr disks. Anomalous changes in intensities of certain peaks as well as wavenumber shifts of some strong absorptions are observed in the DRIFT spectra. The cause of these anomalous features is believed to be the presence of specular reflectance. Various experimental methods for rectifying this problem, such as sample preparation, dilution in inert matrices, etc. are discussed.
引用
收藏
页码:257 / 275
页数:19
相关论文
共 15 条
[1]   EFFECT OF SCATTERING COEFFICIENT ON DIFFUSE REFLECTANCE INFRARED-SPECTRA [J].
FRASER, DJJ ;
GRIFFITHS, PR .
APPLIED SPECTROSCOPY, 1990, 44 (02) :193-199
[2]   DIFFUSE REFLECTANCE MEASUREMENTS BY INFRARED FOURIER-TRANSFORM SPECTROMETRY [J].
FULLER, MP ;
GRIFFITHS, PR .
ANALYTICAL CHEMISTRY, 1978, 50 (13) :1906-1910
[3]  
Griffiths P. R., 1982, ADV INFRARED RAMAN S, V9, P63
[4]   ANOMALOUS DISPERSION EFFECTS IN DIFFUSE REFLECTANCE INFRARED FOURIER-TRANSFORM SPECTROSCOPY - A STUDY OF OPTICAL GEOMETRIES [J].
HEMBREE, DM ;
SMYRL, HR .
APPLIED SPECTROSCOPY, 1989, 43 (02) :267-274
[5]   INFLUENCES OF SURFACE REFLECTIONS ON DIFFUSE REFLECTANCE MEASUREMENTS [J].
KORTE, EH ;
STAAT, H .
JOURNAL OF MOLECULAR STRUCTURE, 1990, 218 :381-386
[6]   INFRARED DIFFUSE REFLECTANCE ACCESSORY FOR LOCAL ANALYSIS ON BULKY SAMPLES [J].
KORTE, EH ;
OTTO, A .
APPLIED SPECTROSCOPY, 1988, 42 (01) :38-43
[7]   APPLICATIONS OF DIFFUSE REFLECTANCE FT-IR TO THE CHARACTERIZATION OF AN E-GLASS FIBER GAMMA-APS COUPLING AGENT SYSTEM [J].
MCKENZIE, MT ;
CULLER, SR ;
KOENIG, JL .
APPLIED SPECTROSCOPY, 1984, 38 (06) :786-790
[8]  
MICHELL AJ, 1988, APPITA J, V41, P375
[9]   INFRARED STUDIES OF HARD AND SOFT WOODS [J].
OWEN, NL ;
THOMAS, DW .
APPLIED SPECTROSCOPY, 1989, 43 (03) :451-455
[10]   EXAMINATION OF A C-BLACK BY VARIOUS FT-IR SPECTROSCOPIC METHODS [J].
ROCKLEY, MG ;
RATCLIFFE, AE ;
DAVIS, DM ;
WOODARD, MK .
APPLIED SPECTROSCOPY, 1984, 38 (04) :553-556