SYNTHESIS AND X-RAY STRUCTURAL CHARACTERIZATION OF THE PHOSPHIDO-BRIDGED TRIOSMIUM CARBONYL CLUSTER [OS3(MU-H)(CO)10(MU-P(C6F5)H] - CLEAVAGE OF A P-C BOND OF A SECONDARY PHOSPHINE

被引：9

作者：

ANG, HG ^{[1
]}

KWIK, WL ^{[1
]}

LEONG, WK ^{[1
]}

JOHNSON, BFG ^{[1
]}

LEWIS, J ^{[1
]}

RAITHBY, PR ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 396卷 / 2-3期

关键词：

D O I：

10.1016/0022-328X(90)85483-F

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the anion [Os3H(CO)11]- with bis(pentafluorophenyl)phosphine, (C6F5)2PH, results in the cleavage of a PC bond and the formation of the bridged phosphido cluster [Os3(μ-H)(CO)10(μ-P(C6F6)H)]. The structure of this product has been confirmed by a single-crystal X-ray diffraction study which shows that the P(C6F5)H ligand and the hydrido bridge the long edge (2.916(1) Å) of the isosceles osmium triangle. © 1990.

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页码：C43 / C46

页数：4

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