Crystal structure of 4,5-bis(3,4,5-trimethoxyphenyl)-2H-1,2,3-triazole methanol monosolvate

被引：2

作者：

Madadi, Nikhil Reddy ^{[1
]}

Penthala, Narsimha Reddy ^{[1
]}

Bommagani, Shobanbabu ^{[1
]}

Parkin, Sean ^{[2
]}

Crooks, Peter A. ^{[1
]}

机构：

[1] Univ Arkansas Med Sci, Coll Pharm, Dept Pharmaceut Sci, Little Rock, AR 72205 USA

[2] Univ Kentucky, Dept Chem, Lexington, KY 40506 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

关键词：

crystal structure; hydrogen bonds; 1,2,3-triazole;

D O I：

10.1107/S1600536814020911

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C20H23N3O6 center dot CH3OH was synthesized by [3 + 2] cycloaddition of (Z)-2,3-bis(3,4,5-trimethoxyphenyl)-acrylonitrile with sodium azide and ammonium chloride in DMF/water. The central nitrogen of the triazole ring is protonated. The dihedral angles between the triazole ring and the 3,4,5-trimethoxyphenyl ring planes are 34.31 (4) and 45.03 (5)degrees, while that between the 3,4,5-trimethoxyphenyl rings is 51.87 (5)degrees. In the crystal, the molecules, along with two methanol solvent molecules are linked into an R-4(4)(10) centrosymmetric dimer by N-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds.

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页码：O1128 / +

页数：10

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