CHEMISTRY OF TRIFLUORAMINE OXIDE .2. REACTIONS WITH INORGANIC SUBSTRATES

被引：14

作者：

FOX, WB

WAMSER, CA

EIBECK, R

HUGGINS, DK

MACKENZI.JS

JUURIK, R

机构：

[1] Industrial Chemicals Research Laboratory, Allied Chemical Corporation, Morristown

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 06期

关键词：

D O I：

10.1021/ic50076a010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Trifluoramine oxide oxidizes N2F4, N2O4, Cl2, and SF4 to NF3, NO2F, GIF, and SF6, respectively, the FsNO being reduced to NOF in each case. These and other reaction studies indicate that oxidations by F3NO involve primarily fluorination rather than oxygenation. Trifluoramine oxide is not readily hydrolyzed by water or aqueous base but is attacked by sulfuric acid. The interaction of F3NO with fluorinated Lewis acids is also described. © 1969, American Chemical Society. All rights reserved.

引用

收藏

页码：1247 / &

相关论文

共 17 条

[1] THE PREPARATION AND SOME REACTIONS OF NITRYL FLUORIDE [J].

AYNSLEY, EE ;

HETHERINGTON, G ;

ROBINSON, PL .

JOURNAL OF THE CHEMICAL SOCIETY, 1954, (MAR) :1119-1124

[2] NITROSYL HEXAFLUOROPLATINATE (V) NO+[PTF6]- - PREPARATION AND MAGNETIC SUSCEPTIBILITY . MAGNETIC SUSCEPTIBILITY OF O+/2 [J].

BARTLETT, N ;

BEATON, SP .

CHEMICAL COMMUNICATIONS, 1966, (06) :167-&

[3] NITROGEN OXIDE TRIFLUORIDE [J].

BARTLETT, N ;

PASSMORE, J ;

WELLS, EJ .

CHEMICAL COMMUNICATIONS, 1966, (07) :213-&

[4] OXIDIZING TRENDS IN 3RD-TRANSITION-SERIES HEXAFLUORIDES [J].

BARTLETT, N ;

BEATON, SP ;

JHA, NK .

CHEMICAL COMMUNICATIONS, 1966, (06) :168-&

[5] INTERACTION OF SOME NITROGEN-FLUORINE COMPOUNDS WITH LEWIS ACIDS [J].

CRAIG, AD .

INORGANIC CHEMISTRY, 1964, 3 (11) :1628-+

[6] CHEMISTRY OF TRIFLUORAMINE OXIDE .I. SYNTHESIS AND CHARACTERIZATION OF F3NO [J].

FOX, WB ;

MACKENZI.JS ;

MCCARTHY, ER ;

HOLMES, JR ;

STAHL, RF ;

JUURIK, R .

INORGANIC CHEMISTRY, 1968, 7 (10) :2064-&

[7] TRIFLUORAMINE OXIDE [J].

FOX, WB ;

MACKENZIE, JS ;

VANDERKOOI, N ;

SUKORNIC.B ;

WAMSER, CA ;

HOLMES, JR ;

EIBECK, RE ;

STEWART, BB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (11) :2604-+

[8]

FOX WB, UNPUBLISHED RESULTS

[9]

HIRSCHMANN R, TO BE PUBLISHED

[10] NITROGEN FLUORIDES AND THEIR ORGANIC DERIVATIVES [J].

HOFFMAN, CJ ;

NEVILLE, RG .

CHEMICAL REVIEWS, 1962, 62 (01) :1-&