PREDICTION OF HIGH-PRESSURE VAPOR-LIQUID-EQUILIBRIA USING ASOG

被引：18
|
作者：
TOCHIGI, K
机构：
[1] Department of Industrial Chemistry, Nihon University, Chiyodaku, Tokyo, 101
来源：
FLUID PHASE EQUILIBRIA | 1995年 / 104卷
关键词：
THEORY; EQUATION OF STATE; CUBIC; MIXING RULES; VAPOR-LIQUID EQUILIBRIA; ASOG; UNIFAC;
D O I：
10.1016/0378-3812(94)02652-H
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
A excess free energy mixing rule with Peng-Robinson EOS modified by Stryjek and Vera has been proposed in order to predict high-pressure VLE using low ASOG parameters. The mixing rule uses a zero-pressure excess free energy and the condition of quardratic composition dependence of second virial coefficient. Prediction is made for binary and ternary systems containing methanol, ethanol, water, and acetone at low and high pressures. With low-pressure ASOG parameters, high-pressure VLE have been predicted.
引用
收藏
页码：253 / 260
页数：8
相关论文
共 50 条
  • [21] High-pressure vapor-liquid and vapor-liquid-liquid equilibria in the carbon dioxide+1-heptanol system
    Secuianu, Catinca
    Feroiu, Viorel
    Geana, Dan
    FLUID PHASE EQUILIBRIA, 2008, 270 (1-2) : 109 - 115
  • [22] THERMODYNAMIC BEHAVIOR OF ELECTROLYTE-SOLUTIONS .2. PREDICTION OF VAPOR-LIQUID-EQUILIBRIA FOR MIXED-SOLVENT ELECTROLYTE SYSTEMS
    LIN, CL
    LEE, LS
    TSENG, HC
    FLUID PHASE EQUILIBRIA, 1993, 90 (01) : 81 - 98
  • [23] MEASUREMENT AND PREDICTION OF VAPOR-LIQUID-EQUILIBRIA FOR A REACTIVE SYSTEM - APPLICATION TO ETHYLENE-OXIDE PLUS NONYL PHENOL
    PATEL, NC
    YOUNG, MA
    FLUID PHASE EQUILIBRIA, 1993, 82 : 79 - 92
  • [24] Comparative study of mixing rules for cubic equations of state in the prediction of multicomponent vapor-liquid equilibria
    SolorzanoZavala, M
    BarraganAroche, F
    Bazua, ER
    FLUID PHASE EQUILIBRIA, 1996, 122 (1-2) : 99 - 116
  • [25] Vapor-liquid equilibria for systems of diethyl carbonate and ketones and determination of group interaction parameters for the UNIFAC and ASOG methods
    Pereiro, AB
    Rodríguez, A
    Canosa, J
    Tojo, J
    FLUID PHASE EQUILIBRIA, 2005, 235 (01) : 83 - 91
  • [26] Measurement and prediction of high-pressure vapor-liquid equilibria for binary mixtures of carbon dioxide plus n-octane, methanol, ethanol, and perfluorohexane
    Tochigi, Katsumi
    Namae, Tooru
    Suga, Tooru
    Matsuda, Hiroyuki
    Kurihara, Kiyofumi
    dos Ramos, M. Carolina
    McCabe, Clare
    JOURNAL OF SUPERCRITICAL FLUIDS, 2010, 55 (02) : 682 - 689
  • [27] High-pressure (vapor plus liquid) equilibria in the (nitrogen plus n-heptane) system
    Garcia-Sanchez, Fernando
    Eliosa-Jimenez, Gaudencio
    Silva-Oliver, Guadalupe
    Godinez-Silva, Armando
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2007, 39 (06) : 893 - 905
  • [28] High-pressure vapor-liquid equilibria of methanol plus propylene: Experimental and modeling with SAFT
    Banaei, M.
    Florusse, L. J.
    Raeissi, S.
    Peters, C. J.
    JOURNAL OF SUPERCRITICAL FLUIDS, 2012, 63 : 25 - 30
  • [29] INFLUENCE OF MOLECULAR SHAPE ON VAPOR-LIQUID-EQUILIBRIA - APPLICATION OF A MODIFIED CHRISTOFORAKOS-FRANCK EQUATION OF STATE
    PLACKOV, D
    MAINWARING, DE
    SADUS, RJ
    FLUID PHASE EQUILIBRIA, 1994, 95 : 371 - 381
  • [30] A new mixing rule for accurate prediction of high pressure vapor-liquid equilibria of gas/large n-alkane systems
    Zhong, CL
    Masuoka, H
    HIGH PRESSURE CHEMICAL ENGINEERING, 1996, 12 : 235 - 240
12345