AN ELECTROSPRAY MASS-SPECTROMETRIC STUDY OF METHYLMERCURY(II) NITROGEN BASE DERIVATIVES AND THEIR LIGAND-EXCHANGE REACTIONS

Electrospray mass spectra have been observed for solutions of a number of methylmercury(II) complexes of the type [MeHgL](+) (L=neutral nitrogen base, e.g. N-methylpyrazoles, bis(pyridin-2-yl)methane, etc.) and PhHg(II) complexes of creatinine and in all cases the intact ion was observed. Electrospray mass spectrometry is a convenient technique with which to investigate ligand exchange reactions in solution, and the reactions of the N-methylpyrazole complex [MeHg(C4H6N2)](+) have been studied with a variety of reagents including other nitrogen bases, phosphines and phosphine sulfides and selenides.