ESTEROLYSIS OF LONG-CHAIN P-NITROPHENYL PICOLINATES BY HYDROPHOBIC ZN2+ COMPLEXES IN THE PRESENCE OF A CATIONIC SURFACTANT

被引：4

作者：

FAIVRE, V ^{[1
]}

BREMBILLA, A ^{[1
]}

LOCHON, P ^{[1
]}

机构：

[1] ECOLE NATL SUPER IND CHIM,CHIM PHYS MACROMOLEC LAB,CNRS,URA 494,1 RUE GRANDVILLE,BP 451,F-54001 NANCY,FRANCE

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1993年 / 85卷 / 01期

关键词：

ALKYL-CHAIN BENZIMIDAZOLE LIGANDS; ESTEROLYSIS RATE; HYDROPHOBIC ZINC(II) COMPLEXES; LONG-CHAIN PICOLINATES; MICELLAR MEDIUM;

D O I：

10.1016/0304-5102(93)87122-O

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The introduction of an increasing alkyl-chain length into a series of homologous esters (5-alkoxy-4'-nitrophenyl picolinates) leads to the enhancement of the overall esterolysis reaction rate catalyzed by lipophilic substituted Zn2+-complexed 2-hydroxymethylbenzimidazoles in the presence of CTAB micelles.

引用

收藏

页码：45 / 56

页数：12

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