Crystal structure of aquabis[2-(1H-benzimidazol-2-yl-kappa N-3)aniline-kappa N]-zinc dinitrate

被引：3
|
作者：
Kim, Yongtae [1 ]
Kang, Sung Kwon [1 ]
机构：
[1] Chungnam Natl Univ, Dept Chem, Taejon 305764, South Korea
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; zinc complex; benzimidazole; hydrogen bonding;
D O I：
10.1107/S2056989015004636
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The cation of the complex title salt, [Zn(C13H11N3)(2)(H2O)(2)(NO3)(2), lies about a twofold rotation axis, which passes through the Znii atom and the atom of the aqua ligand. The Znii atom adopts a distorted trigonal-bipyramidal geometry defined by two N atoms in axial positions [angle = 166.24 (7)degrees], and two N and one O atom in the equatorial plane [range of angles: 115.17 (7)-122.42 (3)]. The dihedral angle between the imidazole and aniline rings is 23.86 (5). In the crystal, N-H- center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds link the components into a three-dimensional network.
引用
收藏
页码：M85 / U93
页数：9
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