Crystal structure of aquabis[2-(1H-benzimidazol-2-yl-kappa N-3)aniline-kappa N]-zinc dinitrate

被引：3

作者：

Kim, Yongtae ^{[1
]}

Kang, Sung Kwon ^{[1
]}

机构：

[1] Chungnam Natl Univ, Dept Chem, Taejon 305764, South Korea

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

关键词：

crystal structure; zinc complex; benzimidazole; hydrogen bonding;

D O I：

10.1107/S2056989015004636

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The cation of the complex title salt, [Zn(C13H11N3)(2)(H2O)(2)(NO3)(2), lies about a twofold rotation axis, which passes through the Znii atom and the atom of the aqua ligand. The Znii atom adopts a distorted trigonal-bipyramidal geometry defined by two N atoms in axial positions [angle = 166.24 (7)degrees], and two N and one O atom in the equatorial plane [range of angles: 115.17 (7)-122.42 (3)]. The dihedral angle between the imidazole and aniline rings is 23.86 (5). In the crystal, N-H- center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds link the components into a three-dimensional network.

引用

页码：M85 / U93

页数：9

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