ALKANE ACTIVATION BY HOMOGENEOUS PALLADIUM COMPLEXES

被引：9

作者：

BEATTIE, JK

MASTERS, AF

SPARKES, ML

机构：

[1] Department of Inorganic Chemistry, University of Sydney, New South Wales

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 1991年 / 5卷 / 06期

关键词：

ALKANE; ACTIVATION; CATALYSIS; ADAMANTANE; ADAMANTANOL; PALLADIUM ACETATE;

D O I：

10.1002/aoc.590050611

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The conversion of adamantane exclusively to 1-adamantyl trifluoroacetate in a refluxing trifluoroacetic acid solution of palladium acetate at 1 atm of air or nitrogen was confirmed. The conversion can be made quantitative. The 1-adamantyl trifluoroacetate was hydrolysed to yield 1-adamantanol in 90% isolated yield. The adamantane functionalization is accompanied by concomitant formation of a palladium mirror.

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页码：521 / 523

页数：3

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