GASEOUS COMPLEXES OF COCL2 WITH PYRIDINE

被引：9

作者：

DAUL, C

EMMENEGGER, F

MLINAR, M

PICCAND, M

机构：

[1] Institute of Inorganic and Analytical Chemistry, University of Fribourg, CH-1700 Fribourg, Pérolles

来源：

INORGANIC CHEMISTRY | 1993年 / 32卷 / 14期

关键词：

D O I：

10.1021/ic00066a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex formation of CoCl2 with pyridine in the gas phase has been studied by vapor pressure measurements and by visible spectroscopy at 290-420-degrees-C. A new, very robust fitting procedure has been used to analyze the data. The data analysis not only indicates the presence of two gaseous complexes, CoCl2(py)2(g) and CoCl2py(g), but in addition gives their individual spectra as well as their enthalpy and entropy of formation. The spectra of the two complexes are rationalized by ligand field calculations using published ligand field and Racah parameters.

引用

页码：2992 / 2995

页数：4

共 16 条

[1] THE THERMAL DECOMPOSITION OF METAL COMPLEXES .3. THE DECOMPOSITION OF SOME PYRIDINE AND SUBSTITUTED-PYRIDINE COMPLEXES OF COBALT(II) HALIDES [J].