CAPDH2, TERNARY HYDRIDE WITH PEROVSKITE RELATED STRUCTURE

被引：30

作者：

BRONGER, W

JANSEN, K

MULLER, P

机构：

来源：

JOURNAL OF THE LESS-COMMON METALS | 1990年 / 161卷 / 02期

关键词：

D O I：

10.1016/0022-5088(90)90040-Q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

CaPdH2 has been synthesized by the reaction of calcium hydride with palladium in a hydrogen atmosphere at 850°C. X-ray investigations on powdered samples and elastic neutron diffraction experiments on a deuterated sample revealed an atomic arrangement, which is related to the perovskite-type structure with a 2 3 occupation of the hydrogen position. We assume a statistical arrangement of linear [PdD22-]-units in the structure. © 1990.

引用

页码：299 / 302

页数：4

共 5 条

[1] NEW CUBIC PHASE IN CALCIUM-PALLADIUM SYSTEM [J].

MENDELSOHN, MH ;

TANAKA, J .

JOURNAL OF THE LESS-COMMON METALS, 1973, 32 (02) :314-316

[2] SYSTEMS LIYPTHX AND LIYPDHX [J].

NACKEN, B ;

BRONGER, W .

JOURNAL OF THE LESS-COMMON METALS, 1977, 52 (02) :323-325

[3] NA2PDH2, A HYDRIDE WITH A NOVEL LINEAR [PDH2] COMPLEX [J].

NOREUS, D ;

TORNROOS, KW ;

BORJE, A ;

SZABO, T ;

BRONGER, W ;

SPITTANK, H ;

AUFFERMANN, G ;

MULLER, P .

JOURNAL OF THE LESS-COMMON METALS, 1988, 139 (02) :233-239

[4] REACTION OF GROUP 8 ELEMENTS WITH BASE METAL OXIDES UNDER HYDROGEN [J].

SCHULZ, H ;

RITAPAL, K ;

BRONGER, W ;

KLEMM, W .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1968, 357 (4-6) :299-&

[5] TERNARY HYDRIDES OF CALCIUM AND STRONTIUM WITH PALLADIUM [J].

STANITSK.C ;

TANAKA, J .

JOURNAL OF SOLID STATE CHEMISTRY, 1972, 4 (03) :331-&

← 1 →