JAHN-TELLER SPLITTINGS IN OPTICAL ABSORPTION SPECTRA OF DIVALENT IRON IN CADMIUM-CHLORIDE-TYPE CRYSTALS

被引：24

作者：

FREEMAN, TE

JONES, GD

机构：

[1] Department of Physics, University of Canterbury, Christchurch

来源：

PHYSICAL REVIEW | 1969年 / 182卷 / 02期

关键词：

D O I：

10.1103/PhysRev.182.411

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Measurements of the Jahn-Teller splittings of the T2g5(D5)→Eg5(D5) optical transition of divalent iron in the near infrared are reported for CdCl2, CdBr2, MgCl2, and MnCl2 crystals containing about 15% divalent iron and for ferrous chloride. The variation of the magnitude of the observed splittings with temperature for the various host crystals is discussed and compared with theoretical predictions. © 1969 The American Physical Society.

引用

页码：411 / &

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