OPTICALLY-ACTIVE BIPYRIDINES IN ASYMMETRIC CATALYSIS

被引：217

作者：

BOLM, C ^{[1
]}

ZEHNDER, M ^{[1
]}

BUR, D ^{[1
]}

机构：

[1] UNIV BASEL,INST ANORGAN CHEM,CH-4056 BASEL,SWITZERLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 02期

关键词：

D O I：

10.1002/anie.199002051

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The bipyridine derivative 1 is a very promising catalyst. It was obtained by asymmetric syn‐thesis, is optically active, and accelerates the addition of diethylzinc to aldehydes. This re‐action affords good yields of product and proceeds with high asymmetric induction (up to 97% ee). (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

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页码：205 / 207

页数：3

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