ENANTIOSELECTIVE SYNTHESIS OF (S)-1-METHYLDODECYL ACETATE, A PHEROMONE OF DROSOPHILA-MULLERI, VIA (-)-SPARTEINE-ASSISTED DEPROTONATION OF 1-DODECANOL

被引：71

作者：

HINTZE, F ^{[1
]}

HOPPE, D ^{[1
]}

机构：

[1] UNIV KIEL,INST ORGAN CHEM,W-2300 KIEL 1,GERMANY

来源：

SYNTHESIS-STUTTGART | 1992年 / 12期

关键词：

D O I：

10.1055/s-1992-26340

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound was synthesized with 98 % ee by enantioselective lithiation and methylation of 1-dodecanol, employing a new protection/activation method for primary alcohols, followed by asymmetric deprotonation of the carbamate.

引用

页码：1216 / 1218

页数：3

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