BINDING-ENERGIES OF WEAKLY BOUND SYSTEMS FROM COMPLEX DIMENSIONAL SCALING

被引:15
|
作者
ROST, JM
机构
[1] Department of Chemistry, University of Washington, BG-10, Seattle
来源
JOURNAL OF PHYSICAL CHEMISTRY | 1993年 / 97卷 / 10期
关键词
D O I
10.1021/j100112a056
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the limit of infinite spatial dimension D, the particles of a system become perfectly localized at the minimum of an effective potential surface. Perturbation theory in 1/D has been used successfully to predict binding energies and electronic structure in the physical three-dimensional space. For weakly bound systems which are neutral if one particle is removed the large dimensional approach has not been applicable because the effective potential surface exhibits a saddle point rather than a global minimum. We show that the extension to complex dimensional scaling can theoretically handle this situation and gives good practical estimates for the binding energies of three-particle Coulomb systems, calculated here as an application of the new method.
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页码:2461 / 2463
页数:3
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