THERMAL FORMATION OF BIALKYLS FROM ALKYLMETALS .4. SYMMETRY REQUIREMENTS FOR REDUCTIVE ELIMINATION FROM DIALKYLMETALS

被引：40
作者：
AKERMARK, B
LJUNGQVIST, A
机构：
[1] Department of Organic Chemistry, Royal Institue of Technology
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 182卷 / 01期
关键词：
D O I：
10.1016/S0022-328X(00)85876-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A general symmetry analysis of reductive elimination from transition metal alkyls has been carried out. It shows that concerted reaction is permitted for various complexes with the configurations d1-d8. Concerted reaction is not permitted for any d0, d9 and d10 systems. For the d1d8 systems the auxiliary ligands are important since they determine the coordination numbers and the spin states of the various complexes. The theoretical predictions agree fairly well with experimental results. © 1979.
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页码：59 / 75
页数：17
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