EXOHORMONES AND ENDOHORMONES .16. SYNTHESIS OF (4E,7Z)-4,7-TRIDECADIEN-1-YL ACETATE, THE SEX-PHEROMONE FOR THE LEAFMINER LITHOCOLLETIS-CORYLIFOLIELLA

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作者
GOCAN, A
GANSCA, L
OPREAN, I
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O6 [化学];
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0703 ;
摘要
The synthesis of the scs pheromone of the leafminer moth, Lithocolletis corylifoliella, (4E, 7Z)-4,7-tridecadien-1-yl acetale, was based on a C-5 + C-8 scheme. The coupling reaction took place between the Grignard reagent of 4-pentin-1-1-oic acid and 1-bromo-2Z-octenc. Propargylic alcohol was used as a starting material in order to ol,lain the two synthons.
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页码:253 / 258
页数:6
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