Investigating the best mixture extraction systems in the separation of rare earth elements from nitric acid solution using Cyanex272, D2EHPA, and 8-Hydroxyquinoline

被引:18
|
作者
Ganji, Seyed Mohammad Seyed Alizadeh [1 ]
Shafaei, Seied Ziaeddin [2 ]
Goudarzi, Nasser [3 ]
Azizi, Asghar [1 ]
机构
[1] Univ Shahrood, Dept Min Petr & Geophys, Shahrood, Iran
[2] Univ Tehran, Coll Engn, Sch Min, Tehran, Iran
[3] Univ Shahrood, Fac Chem, Shahrood, Iran
关键词
Mixture system; separation factor; Cyanex272; D2EHPA; hydroxyquinoline;
D O I
10.1080/12269328.2015.1084243
中图分类号
P [天文学、地球科学];
学科分类号
07 ;
摘要
This study is aimed at determining the optimum mixing ratio and solvent group to extract REEs from nitric leach solution, and the efficiency was tested using three different kinds of extractants, which were prepared to mix three different solvents of Cyanex272, D2EHPA, and HQ. In order to select the best mixture system, different volumes (ml) of solvent extractions were used under optimum conditions (. 05 M concentration and pH of 2). The result indicated that the mixture system of Cyanex272 (8 ml) and D2EHPA (2 ml) had the highest separation factor and enrichment ratio in the separation of rare earth element, especially dysprosium. The degree of performance of mixture systems in separation of the rare earth elements indicated that the best extraction systems were in the order of Cyanex272 (8 ml) and D2EHPA (2 ml) > HQ (2 ml) and D2EHPA (8 ml) > Cyanex272 (8 ml) and HQ (2 ml).
引用
收藏
页码:32 / 38
页数:7
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