MATHEMATICAL SIMULATION OF POLYMERIZATION OF ACRYLAMIDE IN CONCENTRATED AQUEOUS-SOLUTIONS

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作者
IVANOV, VA
KAMENSHCHIKOV, AF
GROMOV, VF
KAMINSKII, VA
BUNE, YV
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O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The model for description of kinetic regularities of radical polymerization of acrylamide in concentrated aqueous solutions taking into account the sharp increase of viscosuty of the reaction system already on initial stages of the process is proposed. The comparison of experimentally determined MM values with calculated ones permitted to evaluate the value of the relative rate constant of the chain transfer to acrylamide molecules.
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页码:15 / 21
页数:7
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