THERMODYNAMICS OF ASSOCIATED SOLUTIONS CONTAINING ANILINE AND METHANOL

被引：15

作者：

NAGATA, I

SANO, M

机构：

[1] Department of Chemistry and Chemical Engineering, Division of Physical Sciences, Kanazawa University, Kanazawa, Ishikawa, 920

来源：

FLUID PHASE EQUILIBRIA | 1992年 / 72卷

关键词：

D O I：

10.1016/0378-3812(92)85023-2

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Excess molar enthalpies of aniline-methanol-benzene mixtures were measured with an isothermal dilution calorimeter at 25-degrees-C. Experimental results for three binary mixtures constituting the ternary mixture are well correlated by use of the UNIQUAC associated-solution model. The ternary experimental results are in close agreement with predicted values obtained from the model having binary parameters. The model is able to satisfactorily predict ternary liquid-liquid equilibria for aniline-methanol-n-hexane and aniline-methanol-n-heptane mixtures using binary information.

引用

页码：147 / 162

页数：16

共 18 条

[1]

[Anonymous], 1980, COMPUTER CALCULATION

[2] A CONTINUOUS LINEAR ASSOCIATION MODEL FOR DETERMINING THE ENTHALPY OF HYDROGEN-BOND FORMATION AND THE EQUILIBRIUM ASSOCIATION CONSTANT FOR PURE HYDROGEN-BONDED LIQUIDS [J].

BRANDANI, V .

FLUID PHASE EQUILIBRIA, 1983, 12 (1-2) :87-104

[3] VAPOR-LIQUID-EQUILIBRIUM DATA FOR BINARY-SYSTEMS OF ANILINE WITH ACETONE, ACETONITRILE, CHLOROBENZENE, METHANOL, AND 1-PENTENE [J].

MAHER, PJ ;

SMITH, BD .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1980, 25 (01) :61-68

[4] HEATS OF MIXING - ALCOHOL-AROMATIC BINARY SYSTEMS AT 25-DEGREES, 35-DEGREES, AND 45-DEGREES C [J].

MRAZEK, RV ;

VANNESS, HC .

AICHE JOURNAL, 1961, 7 (02) :190-195

[5] THERMODYNAMICS OF ALCOHOL-SOLUTIONS - PHASE-EQUILIBRIA OF BINARY AND TERNARY MIXTURES CONTAINING 2 ALCOHOLS [J].

NAGATA, I ;

OHTSUBO, K .

THERMOCHIMICA ACTA, 1986, 102 :185-205

[6] THERMODYNAMICS OF ALCOHOL-SOLUTIONS - EXCESS MOLAR ENTHALPIES OF BINARY AND TERNARY MIXTURES CONTAINING 2 ALCOHOLS [J].

NAGATA, I ;

GOTOH, K .

THERMOCHIMICA ACTA, 1986, 102 :207-222

[7] LIQUID LIQUID EQUILIBRIA FOR THE ACETONITRILE + METHANOL + SATURATED-HYDROCARBON AND ACETONITRILE + 1-BUTANOL + SATURATED-HYDROCARBON SYSTEMS [J].

NAGATA, I .

THERMOCHIMICA ACTA, 1987, 114 (02) :227-238

[8] TERNARY LIQUID LIQUID EQUILIBRIA FOR [(ANILINE + SATURATED-HYDROCARBON) + METHANOL OR ETHANOL] [J].

NAGATA, I .

THERMOCHIMICA ACTA, 1991, 186 (01) :123-130

[9] EXCESS MOLAR ENTHALPIES OF BINARY AND TERNARY MIXTURES FORMED BY METHANOL, 2-BUTANOL AND BENZENE [J].

NAGATA, I ;

TAMURA, K .

FLUID PHASE EQUILIBRIA, 1988, 41 (1-2) :127-139

[10] ON THE THERMODYNAMICS OF ALCOHOL-SOLUTIONS - PHASE-EQUILIBRIA OF BINARY AND TERNARY MIXTURES CONTAINING ANY NUMBER OF ALCOHOLS [J].

NAGATA, I .

FLUID PHASE EQUILIBRIA, 1985, 19 (03) :153-174

← 1 2 →