2EG-]4A2G PHOSPHORESCENCE SPECTRUM OF THE CR3+ ION IN K2NAALF6

被引：60

作者：

GREENOUGH, P ^{[1
]}

PAULUSZ, AG ^{[1
]}

机构：

[1] GEC LTD,HIRST RES CTR,WEMBLEY HA9 7PP,MIDDLESEX,ENGLAND

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 04期

关键词：

D O I：

10.1063/1.437620

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The low temperature emission spectrum of the Cr3+ ion in the cubic lattice K2NaAlF6 has been measured. A detailed analysis of the vibrational structure observed leads to the conclusion that the 2Eg and 4T2g excited states of the CrF63- ion are displaced along the eg, a 1g, and possibly the t2g coordinates. A similar analysis of the emission spectrum of K2NaGaF6:Cr3+ is possible, and values of five of the six internal vibrational modes of the CrF63- ion have been deduced. © 1979 American Institute of Physics.

引用

页码：1967 / 1972

页数：6