OPTIMIZATION OF LIPASE-CATALYZED SYNTHESIS OF CITRONELLYL ACETATE IN SOLVENT-FREE MEDIUM

被引：36

作者：

FONTEYN, F

BLECKER, C

LOGNAY, G

MARLIER, M

SEVERIN, M

机构：

[1] Faculté des Sciences Agronomiques, U.E.R. de chimie générale et organique, Gembloux, B-5030, 2, Passage des Déportés

来源：

BIOTECHNOLOGY LETTERS | 1994年 / 16卷 / 07期

关键词：

D O I：

10.1007/BF00136473

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

Citronellol esterification catalyzed by Candida antarctica lipase is performed with high yields (74%) in a solvent-free medium. The use of dessicants gives a 10% yield enhancement and substrate excess consumption by adding calculated amounts of acetic acid lead to a 80% pure citronellyl acetate. Quantities up to 100 ml are treated with success.

引用

页码：693 / 696

页数：4

共 20 条

[1] LIPASE G-CATALYZED SYNTHESIS OF MONOGLYCERIDES IN ORGANIC-SOLVENT AND ANALYSIS BY HPLC [J].

AKOH, CC ;

COOPER, C ;

NWOSU, CV .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1992, 69 (03) :257-260

[2] LIPASE-CATALYZED SYNTHESIS OF PARTIAL GLYCERIDE [J].

AKOH, CC .

BIOTECHNOLOGY LETTERS, 1993, 15 (09) :949-954

[3] ENZYMATIC ESTERIFICATION OF GLYCEROL .2. LIPASE-CATALYZED SYNTHESIS OF REGIOISOMERICALLY PURE 1(3)-RAC-MONOACYLGLYCEROLS [J].

BERGER, M ;

SCHNEIDER, MP .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1992, 69 (10) :961-965

[4] ENZYMATIC ESTERIFICATION OF GLYCEROL .1. LIPASE-CATALYZED SYNTHESIS OF REGIOISOMERICALLY PURE 1,3-SN-DIACYLGLYCEROLS [J].

BERGER, M ;

LAUMEN, K ;

SCHNEIDER, MP .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1992, 69 (10) :955-960

[5]

BLECKER C, 1994, UNPUB J CHEM TECHNOL

[6] ENZYMATIC-SYNTHESIS OF GERANIOL AND CITRONELLOL ESTERS BY DIRECT ESTERIFICATION IN N-HEXANE [J].

CLAON, PA ;

AKOH, CC .

BIOTECHNOLOGY LETTERS, 1993, 15 (12) :1211-1216

[7]

Gillies B., 1987, In 'Biocatalysis in organic media', edited by Laane, C. et al. Amsterdam, Netherlands

[8]

Elsevier Science Publishers BV. ISBN 0-444-42785-6 [see FSTA (1989) 21 8B67]., P227

[9] SOLVENT SELECTION FOR BIOCATALYSIS IN MAINLY ORGANIC-SYSTEMS - PREDICTIONS OF EFFECTS ON EQUILIBRIUM POSITION [J].

HALLING, PJ .

BIOTECHNOLOGY AND BIOENGINEERING, 1990, 35 (07) :691-701

[10] 1-MONOGLYCERIDE PRODUCTION FROM LIPASE-CATALYZED ESTERIFICATION OF GLYCEROL AND FATTY-ACID IN REVERSE MICELLES [J].

HAYES, DG ;

GULARI, E .

BIOTECHNOLOGY AND BIOENGINEERING, 1991, 38 (05) :507-517

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