CRYSTAL-STRUCTURE OF A NEW MODIFICATION OF SB8F30

被引：3
|
作者：
MINKWITZ, R [1 ]
NOWICKI, J [1 ]
BORRMANN, H [1 ]
机构：
[1] MAX PLANCK INST FESTKORPERFORSCH,W-7000 STUTTGART 80,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 605卷 / 14期
关键词：
ANTIMONY(III)(V) FLUORIDE; (SB2F5+)(SB3F72+)(SBF6-)3; PREPARATION; CRYSTAL STRUCTURE;
D O I：
10.1002/zaac.19916050112
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The modification of Sb8F30, described here, crystallizes in the orthorhombic space group Pca2(1) (No. 29) with a = 1115.7(1), b = 1100.2(1), c = 1917.8(3) pm and Z = 4. Within this complex molecule, the Sb3F7(2+)-cation was identified besides a heavily distorted form of the mixed valent Sb4F17(-)-anion.
引用
收藏
页码：109 / 116
页数：8
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