PROMOTERS FOR THE (ALKYNE)HEXACARBONYLDICOBALT-BASED CYCLOPENTENONE SYNTHESIS

被引：159

作者：

CHUNG, YK

LEE, BY

JEONG, N

HUDECEK, M

PAUSON, PL

机构：

[1] KOREA RES INST CHEM TECHNOL,POB 9,DAEJON,SOUTH KOREA

[2] SEOUL NATL UNIV,DEPT CHEM,SEOUL 151,SOUTH KOREA

[3] UNIV STRATHCLYDE,DEPT PURE & APPL CHEM,GLASGOW G1 1XL,SCOTLAND

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 01期

关键词：

D O I：

10.1021/om00025a036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dimethyl sulfoxide and a variety of other highly polar solvents are shown to promote both inter- and intramolecular cyclopentenone formation from alkenes and (alkyne)hexacarbonyldicobalt complexes. Their use leads to significant changes in both regio- and stereoselectivity when compared to other reaction conditions.

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页码：220 / 223

页数：4

相关论文

共 11 条

[1] USE OF DIETHYLAMINOSULPHUR TRIFLUORIDE (DAST) IN THE PREPARATION OF SYNTHONS OF CARBOCYCLIC NUCLEOSIDES [J].

BIGGADIKE, K ;

BORTHWICK, AD ;

EVANS, D ;

EXALL, AM ;

KIRK, BE ;

ROBERTS, SM ;

STEPHENSON, L ;

YOUDS, P .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1988, (03) :549-554

[2] METHYLENOMYCIN-B - AN EFFICIENT SYNTHESIS FROM (2-BUTYNE)HEXACARBONYLDICOBALT [J].

BILLINGTON, DC ;

PAUSON, PL .

ORGANOMETALLICS, 1982, 1 (12) :1560-1561

[3] THE EFFECT OF ULTRASOUND AND OF PHOSPHINE AND PHOSPHINE-OXIDES ON THE KHAND REACTION [J].

BILLINGTON, DC ;

HELPS, IM ;

PAUSON, PL ;

THOMSON, W ;

WILLISON, D .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 354 (02) :233-242

[4] THE SYNTHESIS OF NITROGEN-HETEROCYCLES VIA THE INTRAMOLECULAR KHAND REACTION - FORMATION OF TETRA-HYDROCYCLOPENTA[C]PYRROL-5(1H)-ONES AND HEXA-HYDROCYCLOPENTA[C]PYRROL-5(1H)-ONES AND HEXAHYDRO-6H-2-PYRINDIN-6-ONES [J].

BROWN, SW ;

PAUSON, PL .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1990, (04) :1205-1209

[5] THE STUDY OF CATALYST EFFECTS ON THE COMPLEXATION OF ARENES WITH CR(CO)6 - AN OVERVIEW [J].

HUDECEK, M ;

GAJDA, V ;

TOMA, S .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 413 (1-3) :155-160

[6]

JEONG N, 1991, SYNLETT, P204

[7]

KAHND IU, 1973, J CHEM SOC P1, P97

[8] CYCLITOL REACTIONS .2. PREPARATION OF BUILDING UNITS FOR SYNTHESIS OF CARBOCYCLIC FURANOSE ANALOGA [J].

PAULSEN, H ;

MAASS, U .

CHEMISCHE BERICHTE-RECUEIL, 1981, 114 (01) :346-358

[9]

PAUSON PL, 1988, ORGANOMETALLICS ORGA, P233

[10]

Schore N. E., 1991, ORG REACTIONS, V40, P1