PROMOTERS FOR THE (ALKYNE)HEXACARBONYLDICOBALT-BASED CYCLOPENTENONE SYNTHESIS

被引：158
作者：
CHUNG, YK
LEE, BY
JEONG, N
HUDECEK, M
PAUSON, PL
机构：
[1] KOREA RES INST CHEM TECHNOL,POB 9,DAEJON,SOUTH KOREA
[2] SEOUL NATL UNIV,DEPT CHEM,SEOUL 151,SOUTH KOREA
[3] UNIV STRATHCLYDE,DEPT PURE & APPL CHEM,GLASGOW G1 1XL,SCOTLAND
来源：
ORGANOMETALLICS | 1993年 / 12卷 / 01期
关键词：
D O I：
10.1021/om00025a036
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Dimethyl sulfoxide and a variety of other highly polar solvents are shown to promote both inter- and intramolecular cyclopentenone formation from alkenes and (alkyne)hexacarbonyldicobalt complexes. Their use leads to significant changes in both regio- and stereoselectivity when compared to other reaction conditions.
引用
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页码：220 / 223
页数：4
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