CYCLOADDITIONS OF CARBONYL OXIDES - A NOVEL STEREOSELECTIVE APPROACH TO 1,3-DIOLS

被引：0
|
作者：
CASEY, M
CULSHAW, AJ
机构：
来源：
SYNLETT | 1992年 / 03期
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中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Carbonyl oxides, formed by ozonolysis of enol ethers [e.g., 1-methoxy-4,8-dimethylnona-1,7-diene (4)], undergo stereoselective intramolecular cycloadditions to unactivated alkenes to give bicyclic dioxolanes. The dioxolanes were easily transformed by catalytic hydrogenation into beta-hydroxycarbonyl compounds and 1,3-diols, thus providing a novel route to 1,3-dioxygenated products.
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页码：214 / 216
页数：3
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