THERMODYNAMIC INVESTIGATION OF THE SYSTEM NI-FE-O

被引：27
作者：
SCHNEIDER, F [1 ]
SCHMALZRIED, H [1 ]
机构：
[1] UNIV HANOVER,SFB 173,W-3000 HANOVER,GERMANY
来源：
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE NEUE FOLGE | 1990年 / 166卷
关键词：
Phase diagrams; Point defect thermodynamics; Solid state electrochemistry;
D O I：
10.1524/zpch.1990.166.Part_1.001
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A thermodynamic investigation has been performed on the solid ternary system Ni - Fe-O, using the high temperature in-situ method of coulometric titration with a solid oxygen ion electrolyte. The boundaries of the wustite field and the spinel field have been determined, and are compared with calculations based on solid solution models. In addition, the nonstoichiometry δ for (Ni, Fe)1-δO3 has been determined experimentally and is interpreted in terms of point defect thermodynamics, assuming singly ionizedcation vacancies and trivalent compensating iron ions to exist in this wustite phase. © R. Oldenbourg Verlag
引用
收藏
页码：1 / 18
页数：18
相关论文
共 22 条
123