MICHAEL ADDITION OF NITROMETHANE TO 3-BUTEN-2-ONE CATALYZED BY POTASSIUM FLUORIDE SUPPORTED ON AL2O3, ZNO, SNO2, SEPIOLITE, ALPO4, ALPO4-AL2O3 AND ALPO4-ZNO

被引：14
作者：
CAMPELO, JM
CLIMENT, MS
MARINAS, JM
机构：
[1] Departamento Quimica Orgánica, Universidad de Córdoba, Cordoba, E-14004, Avda. San Alberto Magno, s/no
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1992年 / 47卷 / 01期
关键词：
D O I：
10.1007/BF02063553
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The Michael addition of nitromethane to 3-buten-2-one has been carried out in the absence of solvent, using potassium fluoride supported on Al2O3, ZnO, SnO2, sepiolite, AlPO4, AlPO4-Al2O3 and AlPO4-ZnO catalysts. We found that KF/ZnO easily performed the Michael addition and thus, ZnO is a better support for the basic reagent than Al2O3. Besides, the Michael addition was not successful with AlPO4 or AlPO4-metal oxide acidic supports.
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页码：7 / 11
页数：5
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