IONIC-CONDUCTIVITY OF POLYMER ELECTROLYTES OBTAINED BY POLYCONDENSATION FROM PEGS - REDOX PROPERTIES INDUCED WITHIN A POLYETHER-ARYL

被引：5

作者：

ALLOIN, F ^{[1
]}

HERRERO, CR ^{[1
]}

SANCHEZ, JY ^{[1
]}

DELABOUGLISE, D ^{[1
]}

ARMAND, M ^{[1
]}

机构：

[1] LAB ION & ELECTROCHIM SOLIDE GRENOBLE,CNRS,F-38402 ST MARTIN DHERES,FRANCE

来源：

ELECTROCHIMICA ACTA | 1995年 / 40卷 / 12期

关键词：

POLYCONDENSATE; REDOX COUPLES; POLYETHER; POLYMER ELECTROLYTE;

D O I：

10.1016/0013-4686(95)00115-U

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Polycondensates were prepared by reacting several polyethyleneglycols, PEG, with 3-chloro-2-chloromethyl-1-propene. After cross-linking and salt dissolution, the ionic conductivity was investigated together with the thermal behaviour of the polymers, according to the ratio of PEG400 blocks in the polycondensates. The best conductivities were obtained for the highest contents in long PEG blocks. 9,10-bis(chloromethyl)anthracene was used in the same way to prepare redox solvating polycondensates. The redox properties of the resulting polycondensates were characterized by cyclic microvoltammetry. An electron hopping transport between redox sites has been set up.

引用

页码：1907 / 1912

页数：6

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