SYNTHESIS AND PROPERTIES OF PENTAFLUOROPHENYLGALLIUM DERIVATIVES - THE PREPARATION OF TRIS(PENTAFLUOROPHENYL)GALLIUM AND ITS ADDUCTS, AND OF BIS(PENTAFLUOROPHENYL)GALLIUM BROMIDE, PENTAFLUOROPHENYLGALLIUM DIBROMIDE, AND TETRABUTYLAMMONIUM TETRAKIS(PENTAFLUOROPHENYL)GALLATE

被引：17

作者：

LUDOVICI, K ^{[1
]}

TYRRA, W ^{[1
]}

NAUMANN, D ^{[1
]}

机构：

[1] UNIV COLOGNE,INST ANORGAN CHEM,GREINSTR 6,W-5000 COLOGNE 41,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 441卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)80167-V

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A complete series of mono-, bis-, tris- and tetrakis-(pentafluorophenyl)gallium compounds has been obtained from the reactions of GaCl3 and GaBr3 With Mg(C6F5)Br. The complexation behaviour of Ga(C6F5)3 . O(C2H5)2 With N-donor molecules has been studied; 1 : 1 adducts with pyridine, diethylamine, tert/butyl amine and aniline as well as the uncomplexed Ga(C6F5)3 and [(n-C4H9)4N][Ga(C6F5)4] have been obtained pure. All the compounds were characterized by NMR spectroscopy, mass spectrometry and elemental analysis, and some IR spectra were recorded.

引用

页码：363 / 371

页数：9

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