LOW-VALENT TITANIUM - A NEW APPROACH TO DEPROTECTION OF ALLYL AND BENZYL GROUPS

被引：47

作者：

KADAM, SM ^{[1
]}

NAYAK, SK ^{[1
]}

BANERJI, A ^{[1
]}

机构：

[1] BHABHA ATOM RES CTR,DIV BIOORGAN,BOMBAY 400085,INDIA

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(00)61209-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel method for the deprotection of allyl and benzyl derivatives of alcohols and phenols by low-valent titanium [Ti(0)] is reported. The possible mechanism is discussed.

引用

页码：5129 / 5132

页数：4

共 13 条

[11] DEALKYLATION OF ALKYL ARYL ETHERS AND SULPHIDES BY DIARYL-PHOSPHIDE AND -ARSENIDE IONS [J].

MANN, FG ;

PRAGNELL, MJ .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (JUL) :4120-&

[12] REMOVAL OF O-BENZYL BLOCKING GROUPS WITH TRIFLUOROACETIC ACID [J].

MARSH, JP ;

GOODMAN, L .

JOURNAL OF ORGANIC CHEMISTRY, 1965, 30 (07) :2491-&

[13] SYNTHETIC METHODS AND REACTIONS .62. TRANSFORMATIONS WITH CHLOROTRIMETHYLSILANE SODIUM IODIDE, A CONVENIENT IN SITU IODOTRIMETHYLSILANE REAGENT [J].

OLAH, GA ;

NARANG, SC ;

GUPTA, BGB ;

MALHOTRA, R .

JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (08) :1247-1251

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