MEDIUM-SIZED CYCLOPHANES .9. FORMATION OF TRANS-10B,10C-DIMETHYL-10B,10C-DIHYDROPYRENES IN THE BROMINATION OF ANTI-8,16-DIMETHYL[2.2]METACYCLOPHAN-1-ENES WITH BROMINE

被引：0

作者：

YAMATO, T

MIYAZAWA, A

KOBAYASHI, K

TASHIRO, M

机构：

[1] KYUSHU UNIV,GRAD SCH ENGN SCI,INST ADV MAT STUDY,6-1 KASUGA KOHEN,KASUGA,FUKUOKA 816,JAPAN

[2] KYUSHU UNIV,GRAD SCH ENGN SCI,DEPT MOLEC SCI & TECHNOL,KASUGA,FUKUOKA 816,JAPAN

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 1991年 / 07期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The bromination of 8,16-dimethyl[2.2]metacyclophan-1-ene with bromine in carbon tetrachloride solution at room temperature for 10 min afforded trans-2,4,7,9-tetrabromo-10b,10c-dimethyl-10b,10c-dihydropyrene in 79% yield; similar reaction of 5,13-dichloro-8,16-dimethyl[2.2]metacyclophan-1-ene at room temperature for 2 h gave trans-2,7-dichloro-4,9-dibromo-10b,10c-dimethyl-10b,10c-dihydropyrene in 25% yield.

引用

页码：182 / 183

页数：2

共 10 条

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