Transition metal-catalyzed dehydrogenation of amines

被引：17

作者：

Broere, Daniel L. J. ^{[1
,2
]}

机构：

[1] Yale Univ, Dept Chem, 225 Prospect St, New Haven, CT 06510 USA

[2] Univ Utrecht, Debye Inst Nanomat Sci, Organ Chem & Catalysis, Univ Weg 99, NL-3584 CG Utrecht, Netherlands

来源：

PHYSICAL SCIENCES REVIEWS | 2018年 / 3卷 / 09期

关键词：

amine dehydrogenation; LOHCs; hydrogen storage; ligand cooperativity; photocatalysis;

D O I：

10.1515/psr-2017-0029

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

This review focuses on the use of homogeneous transition metal complexes for the catalytic dehydrogenation of amines for synthetic purposes, and for hydrogen storage applications. The catalytic dehydrogenation of primary, secondary and cyclic amines is reviewed looking at reaction conditions, different catalysts and common side reactions. Recent developments in this active field of research showcase how cooperative ligands and photocatalysts can overcome the need for noble metals or harsh reaction conditions.

引用

页数：20

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