FLUORIDATED ELEMENTORGANIKA .20. SYNTHESIS OF FLUORMETHYLTRIMETHYLSILANES

被引：16

作者：

BROICHER, V ^{[1
]}

GEFFKEN, D ^{[1
]}

机构：

[1] UNIV HAMBURG,INST PHARMAZEUT CHEM,BUNDESSTR 45,W-2000 HAMBURG 13,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 381卷 / 03期

关键词：

D O I：

10.1016/0022-328X(90)80061-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of the fluoromethyltrimethylsilanes 4 [(H3C)3SiCF2X, 4a: X = Cl; 4b: X = Br; 4c: X = H; (H3C)3SiCFXY, 4d: X = Cl; Y = H; 4e: X, Y = H] is described. The reaction of the tris-(diethylamino)-phosphane (1)/trimethylsilyl-halogenide 3 system with the difluorodihalogenomethanes 2 gives the hitherto unknown 4a,b. The reduction of 4a,b and dichloroflouromethyltrimethylsilane (13) [(H3C)3SiCFCl2] with tris-(n-butyl)-stannane (14) produces 4c-e in fair yields. © 1990.

引用

页码：315 / 320

页数：6

共 12 条

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