SYNTHESES OF HOMOPROAPORPHINES BY PHENOLIC OXIDATIVE COUPLING .2. SEPARATION OF 2 ISOMERIC DIENONES OF HOMOPROAPORPHINES

被引：72

作者：

KAMETANI, T

SATOH, F

YAGI, H

FUKUMOTO, K

机构：

[1] Pharmaceutical Institute, School of Medicine, Tohoku University, Kitayobancho, Sendai

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1968年 / 33卷 / 02期

关键词：

D O I：

10.1021/jo01266a046

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxidation of 1,2,3,4-tetrahydro-7-hydroxy-1-(4-hydroxy-3-methoxyphenethyl)-6-methoxy-2-methylisoquinoline (3) with potassium ferrieyanide or ferric chloride gave a mixture of two isomeric dienones (5a and 5b) which were separated. The methoxy analog of phenethylisoquinoline (4) also gave the dienone 6 by phenolic oxidative coupling reaction. © 1968, American Chemical Society. All rights reserved.

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页码：690 / &

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