BROAD-BAND POLARIZATION-TRANSFER EXPERIMENTS FOR ROTATING SOLIDS

被引：90

作者：

BALDUS, M ^{[1
]}

TOMASELLI, M ^{[1
]}

MEIER, BH ^{[1
]}

ERNST, RR ^{[1
]}

机构：

[1] ETH ZENTRUM,PHYS CHEM LAB,CH-8092 ZURICH,SWITZERLAND

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 230卷 / 4-5期

关键词：

D O I：

10.1016/0009-2614(94)01209-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new type of rotor-synchronized 'R/L-driven' polarization-transfer techniques is introduced and is shown to lead to efficient rare spin polarization transfer over a large range of chemical shifts. It is demonstrated that polarization transfer can proceed via a zero- or double-quantum mechanism depending on the design of the pulse sequence. It is shown experimentally that R/L-driven polarization transfer can be observed not only in isotopically enriched compounds but also in natural abundance (e.g C-13) samples.

引用

页码：329 / 336

页数：8

共 27 条

[1]

ALLA MA, 1978, PISMA ZH EKSO TEOR F, V4, P208

[2]

BALDUS M, 1994, Z NATURFORSCH A, V49, P80

[3] CHEMICAL-SHIFT CORRELATION SPECTROSCOPY IN ROTATING SOLIDS - RADIO FREQUENCY-DRIVEN DIPOLAR RECOUPLING AND LONGITUDINAL EXCHANGE [J].