MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION-METALS .133. METHYLTRIOXORHENIUM AS A CATALYST OF THE BAEYER-VILLIGER OXIDATION

被引：105

作者：

HERRMANN, WA

FISCHER, RW

CORREIA, JDG

机构：

[1] Anorganisch-chemisches Institut der Technischen Universität München, D-85747 Garching

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 94卷 / 02期

关键词：

BAEYER-VILLIGER REACTION; LACTONES; OXIDATION; RHENIUM;

D O I：

10.1016/S0304-5102(94)87043-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Methyltrioxorhenium CH3ReO3 (MTO, 1) is one of the most active catalysts of the Baeyer-Villiger oxidation of cyclic ketones by use of H2O2 as oxidant. In contrast to the chemistry of established molybdenum and tungsten peroxo complexes, the bis(peroxo) complex [CH3ReO(O-2)(2).H2O] reacts stoichiometrically with ketones. The electronic character of the active species was determined by spectroscopy and by application of an oxygen transfer probe.

引用

页码：213 / 223

页数：11

共 38 条

[1] THIANTHRENE 5-OXIDE AS MECHANISTIC PROBE IN OXYGEN-TRANSFER REACTIONS - SUBSTRATE COMPLEXATION IN OXIDATIONS WITH TRANSITION-METAL PEROXIDES [J].