HYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RHODIUM(I) AS AN EFFECTIVE CATALYST FOR THE REGIOSPECIFIC HYDROSILATION OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS

被引：22

作者：

CHAN, TH

ZHENG, GZ

机构：

[1] Department of Chemistry, McGill University, Montreal, Que. H3A 2K6

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 19期

关键词：

D O I：

10.1016/S0040-4039(00)93388-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydridotetrakis(triphenylphosphine)rhodium(I) acts as an effective catalyst for the reactions of alpha,beta-unsaturated carbonyl compounds with silanes to give regioselectively the enol silyl ethers in a 1,4-hydrosilation.

引用

页码：3095 / 3098

页数：4

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