SOME TRIPHENYLPHOSPHINIMINE COMPLEXES OF ZINC, CADMIUM, MERCURY, RHODIUM AND PALLADIUM

被引：24

作者：

ABEL, EW

MUCKLEJOHN, SA

机构：

[1] Department of Chemistry, University of Exeter, Exeter

来源：

INORGANICA CHIMICA ACTA | 1979年 / 37卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)95526-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The in situ alcoholysis of Ph3PNSiMe3 in the presence of anhydrous halides of zinc, cadmium and mercury results in the formation of a range of co-ordination complex of triphenylphosphinimine, Ph3PNH (L). The complexes formed were of three types: i) the trans dimers [(MX2L)2], ii) the cyclic dimers [(MX2L2)2]· (CHCl3)2 and iii) the polymeric (M2X2L3)n. Triphenylphosphinimine complexes of rhodium and palladium results from halogen bridge fission in [{PdCl(η-C3H5)}2] and [{Rh(CO)2Cl}2]. © 1979.

引用

页码：107 / 111

页数：5

共 29 条

[1]

ABEL EW, 1978, Z NATURFORSCH B, V33, P339

[2]

AHUJA IS, 1970, J CHEM SOC A, P2161

[3] NOVEL DEOXYGENATION OF A CARBONYL GROUP OF IRON PENTACARBONYL [J].

ALPER, H ;

PARTIS, RA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 35 (01) :C40-&

[4] 1,2-BIS-(TRIPHENYLPHOSPHORANE-YLIDENE-AMINO)ETHANE AS A BIDENTATE LIGAND IN TRANSITION-METAL COMPLEXES [J].

APPEL, R ;

VOLZ, P .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1975, 413 (01) :45-50

[5]

APPEL R, 1961, Z NATURFORSCH B, V16, P405

[6] PHOSPHINE-IMINATO COMPLEXES OF MOLYBDENUM(V) [J].

BEILHARZ, GR ;

SCOTT, D ;

WEDD, AG .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1976, 29 (10) :2167-2172

[7] MIXED COORDINATION IN CRYSTAL-STRUCTURES OF TERTIARY PHOSPHINE COMPLEXES OF MERCURY(II) CHLORIDE - (ME2ETP)3(HGCL2)2 AND (BUN3P)HGCL2 [J].

BELL, NA ;

GOLDSTEIN, M ;

JONES, T ;

NOWELL, IW .

INORGANICA CHIMICA ACTA, 1978, 28 (02) :L169-L170

[8]

BELL NA, 1976, CHEM COMMUN, P1039

[9] THERMOLYSE SILYLIERTER TETRAZOLE [J].

BIRKOFER, L ;

RICHTER, P ;

RITTER, A .

CHEMISCHE BERICHTE-RECUEIL, 1963, 96 (10) :2750-&

[10]

BOCK H, 1966, Z NATURFORSCH PT B, VB 21, P739

← 1 2 3 →