RADIATIONLESS DECAY IN RHODIUM(I) AND IRIDIUM(I) COMPLEXES - POLARIZATION AND SOLVENT RELAXATION STUDIES

被引：30

作者：

ANDREWS, LJ

机构：

[1] GTE Laboratories Incorporated, Waltham

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1979年 / 83卷 / 25期

关键词：

D O I：

10.1021/j100488a004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Radiationless decay in the complex iridium [cis-1,2-bis(diphenylphosphino)ethylene] chloride and its Rh(I) analogue have been characterized in 1-propanol and glycerol. Decay in the Rh(I) complex and, to a lesser extent, in the Ir(I) complex is controlled by solvent rigidity and not by temperature. Excitation polarization and wavelength-dependent emission decay studies show that neither solute nor solvent rotational relaxation play a role in the decay. © 1979 American Chemical Society.

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页码：3203 / 3209

页数：7

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