(R)-[(R)-3-Benzyl-2-oxooxazolidin-4-yl]-[4-(methylsulfonyl)phenyl] methyl acetate

被引：0

作者：

Li, Feng ^{[1
]}

Zhao, Ming-Zhong ^{[2
]}

Jin, Chun-Hua ^{[1
]}

Zou, Jian-Wei ^{[1
]}

机构：

[1] Zhejiang Univ, Sch Biol & Chem Engn, Ningbo Inst Technol, Ningbo 315100, Zhejiang, Peoples R China

[2] Ningbo Ocean & Fishery Bur, Ningbo 315100, Zhejiang, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

关键词：

data-to-parameter ratio = 14.3; mean σ(C-C) = 0.004 A°; R factor = 0.035; single-crystal X-ray study; T = 296 K; wR factor = 0.091;

D O I：

10.1107/S1600536814009106

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The structure of the title compound, C20H21NO6S, is of interest with respect to its antibacterial properties. The oxazolidine ring makes dihedral angles of 79.63 (14) and 56.16 (12)degrees with the phenyl and benzene rings, respectively, while the phenyl and benzene rings make a dihedral angle of 64.37 (13)degrees. In the crystal, non-classical C-H center dot center dot center dot O hydrogen bonds link adjacent molecules along the c axis.

引用

页码：O606 / +

页数：9

共 7 条

[1]

Bruker, 2000, SMART SAINT SADABS

[2] ON ENANTIOMORPH-POLARITY ESTIMATION [J].

FLACK, HD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881

[3]

JOMMI G, 1985, GAZZ CHIM ITAL, V115, P653

[4] An efficient enantioselective synthesis of florfenicol via a vanadium-catalyzed asymmetric epoxidation [J].

Li, Feng ;

Wang, Zhong-Hua ;

Zhao, Lei ;

Xiong, Fang-Jun ;

He, Qiu-Qin ;

Chen, Fen-Er .

TETRAHEDRON-ASYMMETRY, 2011, 22 (12) :1337-1341

[5]

Nagabhushan T. L., 1980, CHEM ABSTR, V94

[6] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[7] Inversion of secondary chiral alcohols in toluene with the tunable complex of R3N-R′COOH [J].

Shi, Xiao-Xin ;

Shen, Chun-Li ;

Yao, Jian-Zhong ;

Nie, Liang-Deng ;

Quan, Na .

TETRAHEDRON-ASYMMETRY, 2010, 21 (03) :277-284

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