A DIMERIC AUTOXIDATION PRODUCT OF 2,3-DIMETHYLINDOLE

被引：22

作者：

BERTI, G

DASETTIM.A

DICOLO, G

NANNIPIERI, E

机构：

[1] Institutes of Organic Chemistry and Pharmaceutical Chemistry, University of Pisa

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 19期

关键词：

D O I：

10.1039/j39690002703

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A product formed in the autoxidation of 2,3-dimethylindole and in the dimerization of 2,3-dimethyl-3-hydroxy-3H-indole has been identified as 3,3a,4,8b-tetrahydro-3′,3a,8b-trimethylspiro-[2H-furo[3,2-6]indole-2, 2′-indoline]-3′-ol (V). on the basis of u.v., i,r., n.m.r., mass spectral, and chemical evidence. Several reactions of (V). involving reduction, cleavage, and rearrangements to pyrrolo[1,2-a:5,4-b′]di-indole derivatives are presented.

引用

页码：2703 / +

页数：1

共 15 条

[1] PEROXIDES OF TETRAHYDROCARBAZOLE AND RELATED COMPOUNDS .6. SOME INDOLENINYL HYDROPEROXIDES [J].